Name | 1,2-Bis(diphenylphosphinoethane)nickel(II) chloride |
Synonyms | DPPE.NiCl2 [Bis(diphenylphosphino)ethane]dichloronickel 1,2-Bis(diphenylphosphino)ethanedichloronickel 1,2-Bis(diphenylphosphinoethane)nickel(II) chloride Dichloro-1,2-bis(diphenylphosphino)ethanenickel(II) DICHLORO[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]NICKEL(II) 1,2-BIS(DIPHENYLPHOSPHINE)ETHANE NICKEL(II) CHLORIDE 1,2-BIS(DIPHENYLPHOSPHINO)ETHANE NICKEL(II) CHLORIDE 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride DICHLORO[BIS(1,2-DIPHENYLPHOSPHINO)ETHANE]NICKEL(II) [1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]DICHLORONICKEL(II) [1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]NICKEL(II) DICHLORIDE |
CAS | 14647-23-5 |
EINECS | 629-489-4 |
InChI | InChI=1/C26H24P2.2ClH.Ni/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2 |
Molecular Formula | C26H24Cl2NiP2 |
Molar Mass | 528.02 |
Melting Point | 263-265°C(lit.) |
Boling Point | 514.8°C at 760 mmHg |
Flash Point | 281.7°C |
Water Solubility | insoluble |
Solubility | Chloroform, Methanol (Sparingly) |
Vapor Presure | 3.38E-10mmHg at 25°C |
Appearance | Orange to Red Crystal |
Color | orange |
Exposure Limit | NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3 |
Storage Condition | Inert atmosphere,2-8°C |
MDL | MFCD00013313 |
Use | Organometallic catalysts. |
Risk Codes | R45 - May cause cancer R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R36/37/38 - Irritating to eyes, respiratory system and skin. R42/43 - May cause sensitization by inhalation and skin contact. R40 - Limited evidence of a carcinogenic effect |
Safety Description | S53 - Avoid exposure - obtain special instructions before use. S22 - Do not breathe dust. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 - Wear suitable protective clothing. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S52 - Not recommended for interior use on large surface areas. |
WGK Germany | 3 |
TSCA | No |
HS Code | 29319090 |
use | organometallic catalyst. As a catalyst, used in organic synthesis such as C- C/C-N/C-O coupling reactions |